THE INDEPENDENT PARTICLE MODEL FOR MANYELECTRON SYSTEM. II. SYMMETRY PROPERTIES AND CRITERIA FOR THE VALIDITY OF THE INDEPENDENT PARTICLE MODEL.
Abstract
Contents: Symmetry and orthogonality properties of the orbitals (Symmetry of the 'best density' approximation, Definition and properties of 'open' and 'closed shell' states, The principle of doubly filled orbitals and its limitations, Symmetry of the 'best energy' approximation, Symmetry of the 'best overlap' approximation); Conditions for the validity of the independent particle model (Comparison with the true first order density matrix, Overlap with the true wave funtion, The independent particle model for closed and open shell states); On localized orbitals (Localizability and independence of quantum mechanical systems, Definition of 'localized orbitals').
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 01, 1964
- Accession Number
- AD0625213
Entities
People
- Vedene H. Smith Jr.
- Werner Kutzelnigg
Organizations
- Uppsala University