ORDER OF ELECTROPHILIC SUBSTITUTION IN 1,2DICARBACLOVODODECABORANE (12) AND NMR ASSIGNMENT.

Abstract

Experimental evidence is presented that o-B10C2H12 brominates under Friedel-Crafts conditions first at positions 9 and 12, and then at 8 (10). Together with existing evidence that chlorination under photochemical conditions substitutes last at B atoms 3 and 6, a unique assignment of the B11 nuclear magnetic resonance spectrum is now possible, and a comparison with the molecular orbital predictions is presented.

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1966
Accession Number
AD0626001

Entities

People

  • G. D. Vikers
  • H. Schroeder
  • J. A. Potenza
  • W. N. Lipscomb

Tags

DTIC Thesaurus Topics

  • Chlorination
  • Magnetic Resonance
  • Motion
  • Nuclear Magnetic Resonance
  • Resonance
  • Spectra
  • Spin Resonance

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Systems Analysis and Design

Technology Areas

  • Space