INVESTIGATION OF CATALYTIC THERMAL OXIDATIVE DEGRADATION OF ORGANIC POLYMERS AT ELEVATED TEMPERATURES.

Abstract

The basic mechanisms of degradation of organic polymers at elevated temperatures in contact with certain metals was investigated. The areas of study included migration of metal into polymers, the role of metal oxide films in degradation, polymer-metal reactions, and inhibition of degradation by the use of inert metal coatings. The polymers considered were epoxies, phenolics, and polybenzimidazole. The metals used were aluminum, iron, and stainless steel. Composite configurations evaluated were lap shear specimens and fine metal powders dispersed in the polymers. The experimental techniques used were mass spectrometry, neutron activation analysis, infrared absorption, electron paramagnetic resonance, thermochemiluminescence, and vapor phase chromatography. (Author, modified-PL).

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1965
Accession Number
AD0626847

Entities

People

  • A. L. Speece
  • D. G. Flom
  • Gudrun Schmidt

Organizations

  • General Electric

Tags

DTIC Thesaurus Topics

  • Degradation
  • Electron Paramagnetic Resonance
  • Mass Spectrometry
  • Metal Coatings
  • Metal Oxides
  • Metals
  • Neutron Activation
  • Oxide Films
  • Oxides
  • Paramagnetic Resonance
  • Polymers
  • Powder Metals
  • Resonance
  • Spectrometry
  • Stainless Steel
  • Vapor Phases

Readers

  • Polymer Science and Engineering.
  • Polymer Science and Technology
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics