OXIDATION AND CHEMILUMINESCENCE OF TETRAKIS (DIMETHYLAMINO) ETHYLENE. I. REVERSIBLE REACTIONS OF OXYGEN WITH TETRAKIS (DIMETHYLAMINO) ETHYLENE AND N-DECANE

Abstract

The solubility and heat of solution of oxygen in n-decane and tetrakis (dimethylamino) - ethylene (TMAE) were measured and found to be almost equal. The spectrally measurable interaction species, TMAE-02 and n-C10H22-02, are shown to have very low enthalpy of formation (-1.2 and -0.4 kcal.). Thus, in nonpolar media the good electron donor TMAE and poor electron donor n-decane react similarly with oxygen.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1965
Accession Number
AD0626925

Entities

People

  • Aaron N. Fletcher
  • Carl A. Heller

Organizations

  • Naval Air Weapons Station China Lake

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Abstracts
  • Alkenes
  • Base Lines
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Classification
  • Electron Donors
  • Electrons
  • Enthalpy
  • Ethylenes
  • Heat Of Solution
  • Hydrocarbons
  • Security
  • Solubility
  • Spectra

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Electrochemical Surface Science
  • Organic Chemistry

Technology Areas

  • Microelectronics