USE OF EPR (ELECTRON PARAMAGNETIC RESONANCE) FOR THE STUDY OF ACTIVE CENTERS IN LIQUID PHASE OXIDATION REACTIONS,

Abstract

By the method of electron paramagnetic resonance cumene peroxide radicals were detected in the reaction of cumene oxidation, catalyzed by cobalt stearate or initiated azobisisobutyronnitrile and dicyclohexlpercarbonate. Stationary concentrations of radicals were measured at various initiation rates in conditions of going oxidation reaction. The concentration of peroxide radicals, calculated by known values of rates of initiation and by the value of recombination velocity constant, are measured. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 03, 1966
Accession Number
AD0627278

Entities

People

  • V. F. Tsepalov
  • V. Ya. Shlyapintokh
  • Ya. A. Lebedev

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Electron Paramagnetic Resonance
  • Electrons
  • Liquid Phases
  • Liquids
  • Magnetic Resonance
  • Motion
  • Oxidation
  • Paramagnetic Resonance
  • Peroxides
  • Phase
  • Physical Properties
  • Resonance
  • Stationary
  • Stearates

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Organic Chemistry

Technology Areas

  • Microelectronics