COMPLEX HYDRIDES AND ZEROVALENT DERIVATIVES OF TRANSITION METALS.
Abstract
The following papers are included in whole or in summary: Hydridocomplexes of transition metals (description of compounds of the type MeH(DPE)2 (Me = Co, Rh; DPE = C2H2 /P (C6H5)3/2 and of /CoH2(DPE)2/ClO4); Basic behaviour of platinum (O) derivatives (the reaction PtL3 + HCl = /PtHL3/Cl and PtHL3/Cl = PtHL2Cl+L/L = (C6H5)3P/ are described and discussed); Tricarbonyl-and hydridotricarbonyl-bistriphenylphosphinerhenium (the reaction ReH5L3 + CO = ReH(CO)3L2+2H2;l/l - p9c6H5)3/ and ReH(CO)3L2 to Re(CO)3L2 (monomeric paramagnetic) are described); Novel rhenium triphenylphosphine compounds (description of the preparation and properties of the new hydrides ReH5L2 and ReH5L3/L = P(C6H5)3/); Triphenylphosphine gold (O) gold (I) compounds (the preparation and properties of the compounds /Au5L4/ X /L = P(C6H5)3, X = Cl, NO3, ClO4, B(C6H5)4, SnCl3/ and Au3L2 X /X = I, CN, SnI3/ are described and discussed); New triphenylphosphine iridium compounds (description of an insaturated hydride IrH3L2 /L = P(C6H5)3/, of the carbonylhydrides IrH3(CO)L2 and IrH(CO)L2, of a cationic carbonylderivative /Ir(CO)3L2/ClO4 and of a metallorganic compound Ir(CO2Me)(CO)2L2.
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 01, 1965
- Accession Number
- AD0627812
Entities
People
- Lamberto Malatesta
Organizations
- University of Milan