THE THERMODYNAMICS OF THE ZIRCONIA/ZIRCONIUM-OXYGEN VAPOR SYSTEM,

Abstract

The study reports the thermodynamic investigation of zirconia, Zr02, over a range of temperatures up to 6000 K and pressures up to 1000 atmospheres. Two sets of equilibrium composition equations are usedone representing a pure gas phase, the other a heterogeneous system of gas and condensed (i.e., solid or liquid) zirconia. The gas phase of the heterogeneous chemical system, like the homogeneous gas phase, comprises five gaseous zirconium-oxygen species. The results of the computational program are presented in both tabular and graphic form. The latter is a conventional Mollier diagram in which specific enthalpy is plotted against specific entropy, with cross plots of temperature, pressure, and molecular weight or moles of condensed irconia. (Author)

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1966
Accession Number
AD0629570

Entities

People

  • F. J. Krieger

Organizations

  • RAND Corporation

Tags

DTIC Thesaurus Topics

  • Arrhenius Equation
  • Atmospheres
  • Enthalpy
  • Entropy
  • Equations
  • Equations Of State
  • Gas Laws
  • Ideal Gas Law
  • Mathematics
  • Molecular Weight
  • Physical Properties
  • Thermodynamic Properties
  • Thermodynamics
  • Zirconium

Readers

  • Combustion science or combustion engineering.
  • Surface Engineering/Surface Coating Technology.