POLYMERIC SULFUR-, PHOSPHORUS-, CARBON NITROGEN - COMPOUNDS

Abstract

The following bi-functional compounds were synthesized as starting materials for the synthesis of inorganic polymers with sulphur-nitrogen-carbon bonds: Sulfuryl-diisocyanate, O2S(NCO)2; amidosulfuric acidisocyanate, H2NSO2NCO; chlorosulfuryl-isocyanate, C1SO2NCO; fluorosulfuryl-isocyanate, FSO2NCO; imido-bis-sulfuric acid chloride, HN(SO2C1)2, and imido-bis-sulfuric acid fluoride, HN(SO2F02. The polyaddition of diamines and diols with O2S(NCO)2 results in polymers which are not very stable to temperature and hydrolysis. The polymers found by reaction of H2NSO2NCO with urea and sulfamide, O2S(NH2)2, likewise, are not very stable. In the field of the phosphorus-nitrogen- compounds the synthesis of triphenylphosphine-imines and of N-halogen-phosphine imines is described. Further experiments deal with antimony-nitrogen compounds and their reactions.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1965
Accession Number
AD0629761

Entities

People

  • A. Hauss
  • G. Eisenhauer
  • H. Gerber
  • R. Appel
  • W. Heinzelmann

Organizations

  • Heidelberg University

Tags

Communities of Interest

  • Counter IED
  • Energy and Power Technologies
  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Acid-Base Indicators
  • Chemical Analysis
  • Chemical Synthesis
  • Chemistry
  • Cyanides
  • Dielectric Gases
  • Heat Energy
  • Indicator Dyes
  • Organic Chemistry
  • Sulfur Compounds

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Marine Propulsion Engineering and Naval Architecture
  • Polymer Science and Technology