CARBORANE-SILOXANE ELASTOMERS

Abstract

The preparation of dicarboranyl alkanes by carboranylation of diacetylenic compounds and by alkylation of metallo carborane compounds was investigated. o-Carborane derivatives of such compounds were prepared by carboranylation of acetylenic compounds. Alkylation reactions yielded o- carborane exocycles and m-carborane low polymers. A monomer, bis(1- chlorodimethylsilyl-o-carboran-2-yl) propane was prepared and its thermal isomerization to the m-carborane derivative was attempted.

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Document Details

Document Type
Technical Report
Publication Date
Feb 18, 1966
Accession Number
AD0629891

Entities

People

  • Joseph Green

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Abstracts
  • Alkylation
  • Chemical Reaction Properties
  • Chemical Reactions
  • Classification
  • Contractors
  • Contracts
  • Controlled Atmospheres
  • Elastomers
  • Equations
  • Infrared Spectra
  • Materials
  • Molecular Weight
  • New Jersey
  • Polymers
  • Precursors
  • Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology