PHYSICAL AND PREPARATIVE STUDIES OF MOLYBDENUM AND TUNGSTEN COMPLEXES.
Abstract
Several new molybdenum complexes containing chelated 8-hydroxy-quinolinato ligands, including (MoCl(C5H5N) (C9H6NO)2) and (MoCl2(C5H5N)2(C9H6NO) and three oxomolybdenum(V) derivatives were prepared and studied. A cationic molybdenum(III) species containing chelated ethylenediamine and a cationic tungsten(IV) species containing chelated 2,2(1)-bipyridine were also synthesized. Other preparative studies included photochemical investigations with tungsten(IV). The complex formerly designated as K2MoCl5H2O by other workers was shown to have less than enough potassium for such a formula, the spectra of K3MoCl6 as currently in the literature has been shown to be incorrect, and the apparent discrepancy in the literature concerning the tetrazole complex Fe(C2F3N4)2.2H2O was explained. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1966
- Accession Number
- AD0631398
Entities
People
- Ronald D. Archer
Organizations
- Tulane University of Louisiana