STUDIES OF COMPLEX PERCHLORATES.

Abstract

The Raman spectrum of crystalline nitronium perchlorate exhibits ten wall resolved lines plus an additional tentative line appearing as a weak shoulder. The infrared spectrum, with sodium chloride optics, contains moderately intense absorptions at 940 cm1 and 2300 cm1 and a strong broad absorption in the region of 1100 cm1 which shows some tendency to resolve into three peaks. The spectra have been interpreted in terms of structural features shown by X-ray structure data. In addition, an interpretation is given correlating the bending mode of the nitronium ion with cation-anion interaction in Crystalline nitronium salts.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1966
Accession Number
AD0634105

Entities

People

  • A. D. Mcelroy
  • C. R. Guibert
  • H. F. Klodowski
  • M. D. Marshall

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Air Force
  • Ammonium Perchlorate
  • Chemical Products
  • Chemical Synthesis
  • Chemistry
  • Chlorine
  • Chlorine Compounds
  • Crystal Structure
  • Dielectric Gases
  • Diffraction
  • Dioxides
  • Heat Energy
  • Heat Of Formation
  • Nitrogen Oxides
  • Oxygen
  • Perchlorates
  • Solid Rocket Oxidizers

Readers

  • Aerial Delivery - Logistics and Supply Chain Management.
  • Materials Science and Engineering.