RESEARCH ON CHEMISTRY OF 03F2 AND 02F2.
Abstract
The reactions of HNF2 with (CH3)3A1 and with B2F4 and O2F2 with SO2 and with NO2 were studied. The product of the reaction of HNF2 with (CH3)3A1 was examined by low-temperature infrared spectroscopy. The initial product is believed to be a coordination compound, HNF2.A1(CH3)3, which decomposes at -80C and above to form (CH3)2A1NF2. In the HNF2- B2F4 system, negative deviations from ideality were observed, although a stable adduct could not be isolated. The reaction of SO2 with O2F2 produced in addition to SO2F2, interesting minor products, FSO2OF and FSO2OOF. The mechanism of the formation of these products was studied by the use of NMR analysis of the products. The reactions of SO2 with FSO2OF and FSO2OOF were studied; F2S2O5 was produced in both cases. The reactions of NO2 with O2F2 were studied. FNO3 was not formed, but only simple fluorination occurred, resulting in FNO2. The products of the reaction of O3F2 with SO2 were essentially the same as those obtained with O2F2, except that the relative quantities were different.
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 18, 1966
- Accession Number
- AD0634440
Entities
People
- Irvine J. Solomon
Organizations
- IIT Research Institute