THE CHEMICAL EFFECTS OF IRRADIATED TRIPLE-BOND COMPOUNDS.
Abstract
The radiation chemistry of acetonitrile, propionitrile, and fifteen alkynes was studied using three different experimental approaches: product analysis (PA), electron spin resonance spectrometry(ESR), and mass spectrometry (MS). The results of each study are discussed in terms of reactions proceeding through energetic intermediates. The ESR and MS studies discuss the intermediates responsible for the product distribution found in the PA study. Topics of discussion include phase effects, extent of hydrogen evolution, toxic product yields, cyclization reactions, induced polymerization, and radiation protection. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Apr 01, 1966
- Accession Number
- AD0634859
Entities
People
- Larry A. Harrah
- Roger E. Rondeau
Organizations
- Air Force Research Laboratory