COBALT-60 RADIOLYSIS OF SOLID ETHYL IODIDE.
Abstract
Glass and polycrystalline ethyl iodide at 77K were irradiated with cobalt 60. Yields of free radicals were measured with an electron paramagnetic resonance spectrometer. G values for radicals in glass and polycrystalline phases were 1.53 and 0.33. Hydrocarbon reaction products were separated by Toepler pumping and measured with a mass spectrometer. Products containing iodine were measured by spectrophotometric methods. Ethene-ethane and hydrogen iodide-iodine product ratios were much higher in the polycrystalline phase than in the glass phase, and higher in the glass phase than in previous results from the liquid phase. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Apr 01, 1966
- Accession Number
- AD0634912
Entities
People
- G. L. Hermann
- L. A. Harrah
Organizations
- Air Force Research Laboratory