VAPOR PHASE GROWTH OF RUBY MONOCRYSTALS.

Abstract

The technique of preparing large, high perfection ruby monocrystals by vapor phase growth was further investigated and developed. A device was incorporated into the system which increased control of total pressure during crystal growth. Ruby crystals were successfully grown using chromium chloride and chromium carbonyl as sources of chromium vapor. Positioning the ruby crystal such that the longitudinal axis was perpendicular rather than parallel to the impinging reactant gas stream was investigated. Oxidation potential was determined to be an important process variable affecting Cr2O3 concentration. Laser oscillation of a vapor-grown ruby compared to Verneuil and Czochralski-grown rubies showed it to be of high optical perfection. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1966
Accession Number
AD0638007

Entities

People

  • Philip S. Schaffer

Tags

DTIC Thesaurus Topics

  • Chlorides
  • Chromium
  • Crystal Growth
  • Crystallization
  • Crystals
  • Oscillation
  • Oxidation
  • Phase
  • Single Crystals
  • Vapor Phases

Readers

  • Combustion science or combustion engineering.
  • Electromagnetic Wave Scattering and Antenna Radiation Engineering
  • Materials Science and Engineering.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition