TEMPERATURE DEPENDENCE OF THE ABSORPTANCE OF AMMONIA NEAR 850/CM.

Abstract

The equipment and experimental techniques used to observe the temperature dependence of absorptance in a small region of the 950/cm band of ammonia are described. The integrated absorptance of two spectral lines was measured at 214K and 300K for samples of pure ammonia and samples of ammonia broadened with nitrogen. The results are presented as plots of total absorptance for the small spectral region versus absorber concentration u and total pressure P. An equivalent pressure Pe is expressed in terms of a self-broadening coefficient B which is function of the ratio of the optical collision diameters. Self-broadening coefficients are determined at 214K and 300K. Integrated absorptances at 300K are compared with those obtained for samples at 214K to determine whether the temperature dependence is that predicted by the Lorentz theory. (Author)

Document Details

Document Type
Technical Report
Publication Date
May 01, 1966
Accession Number
AD0638747

Entities

People

  • A. K. Rogers
  • E. R. Manring
  • R. R. Patty

Organizations

  • North Carolina State University

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Coefficients
  • Collisions
  • Diameters
  • Nitrogen
  • Nitrogen Compounds
  • Spectral Lines

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Molecular Photonics/Laser Physics
  • Thermal Physics or Thermal Science.