RESEARCH ON PHOSPHORUS-NITROGEN-SILICON COMPOUNDS.
Abstract
The reactions of hexamethyldisilazane and trimethyl-N-methyl-aminosilane with amides and hydrazides of esters of phosphoric acid result in heterolysis of Si-N-compounds and trimethylsilyl-amides or -hydrazides of the corresponding phosphoric acid are formed. Monochlorides of esters of phospheric acid also react with hexamethyldisilazane under heterocyclic fission of the Si-N-compound, while the reaction of trimethyl-N-methylamino-silane results in the substitution of the H-atom attached to the N-atom without any fission of the Si-N-compound. Derivates of the dichlorophospheric acid are obtained from silazane and OPC13. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 15, 1959
- Accession Number
- AD0639929
Entities
People
- Margot Becke-goehring
Organizations
- Heidelberg University