STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. XVI. SYNTHESIS OF ORGANOGERMANIUM COMPOUNDS CONTAINING THE P-PHENYLENE GROUP. SOME INFRARED CHARACTERISTICS OF P-PHENYLENE DERIVATIVES OF SILICON, GERMANIUM, TIN AND LEAD.
Abstract
A few oligomeric and polymeric p-phenylenegermanes have been prepared by Wurtz-type condensation reactions from p-chlorophenyl and chloro-germanes. The oligomerio and polymeric products obtained have been characterized by infrared spectroscopy, elementary analysis and molecular weight determinations. Infrared spectra in the rocksalt region of phenyl and p-phenylene derivatives of silicon, germanium, tin and lead are discussed. The spectra of the p-phenylene compounds show some characteristic absorption bands shifting to lower frequencies as the weight of the metal atoms in the molecule increases. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 20, 1964
- Accession Number
- AD0640547
Entities
People
- A. J. Leusink
- G. J. M. Van Der Kerk
- H. A. Budding
- J. G. Noltes