STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. XII. LINEAR POLYADDITION POLYMERS DERIVED FROM P-PHENYLENE-BIS-(DIMETHYLTIN HYDRIDE) AND DIPHENYLTIN DIHYDRIDE.
Abstract
The preparation and characterization of linear organometallic polymers containing tin or tin and lead in the polymer main chain is described. These polymers were obtained by polyaddition reactions from p-phenylene-bis-(dimethyltin hydride) and various di-olefinic, acetylenic and di-acetylenic compounds. Reactions of this novel organotin hydride were carried out with p-styrenyl derivatives of germanium, tin and lead, leading to monomeric compounds containing four hydrocarbon-linked metal atoms. Furthermore, linear polyesters and polyamides containing organotin radicals in the polymer backbone were prepared from diphenyltin dihydride and difunctionally-unsaturated esters and amides. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 24, 1963
- Accession Number
- AD0640549
Entities
People
- A. J. Leusink
- G. J. M. Van Der Kerk
- J. G. Noltes