TRIPHENYLSILOXY DERIVATIVES OF BIS-CYCLOPENTADIENYL TITANIUM.

Abstract

Contrary to a report in the literature one or two chlorine atoms in bis-cyclopentadienyl titanium dichloride may be replaced by triphenylsiloxy groups with retention of the cyclopentadienyl groups. Orange-colored triphenyl-siloxy-bis-cyclopentadienyl titanium chloride (m.p. 210-212C) and yellow-colored bis-triphenylsiloxy-bis-cyclopentadienyl titanium (m.p. 208-210C) were isolated in good yield. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1961
Accession Number
AD0640550

Entities

People

  • G. J. M. Van Der Kerk
  • J. G. Noltes

Tags

DTIC Thesaurus Topics

  • Chlorides
  • Chlorine
  • Chlorine Compounds
  • Elements
  • Halogen Compounds
  • Halogens
  • Literature
  • Titanium

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Organic Chemistry