STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. VIII. SYNTHESIS OF LINEAR ORGANOTIN POLYMERS FROM ORGANOTIN DIHYDRIDES AND ACETYLENIC COMPOUNDS.

Abstract

Linear organotin polymers with molecular weights in the range of 45000 to 100000 were obtained by poly-addition reactions involving organotin dihydrides and alpha, omega-diynes, such as hexadiyne-1,5, nonadiyne-1,8, and 1,4-diethynylbenzene. A number of 1-stannacycloheptadiene-2,6 derivatives (cyclic monomers derived from hexadiyne-1,5) were isolated. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1961
Accession Number
AD0640551

Entities

People

  • G. J. M. Van Der Kerk
  • J. G. Noltes

Tags

DTIC Thesaurus Topics

  • Addition Reactions
  • Chemical Phenomena
  • Chemistry
  • Molecular Weight

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology