STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. VII. SYNTHESIS OF SOME HETERO-POLYMERS CONTAINING GERMANIUM, TIN, AND LEAD IN THE MAIN POLYMER CHAIN.
Abstract
It was shown that di-p-styrenyl derivatives of germanium, tin, and lead as well as 1,4-divinylbenzene and 3,9-divinylspirobi (meta-dioxane) react with diphenyltin dihydride to yield linear poly-addition polymers containing tin or tin and germanium or lead in the main polymer chain. The polmeric products were characterized by infrared spectroscopy, analytical data and molecular weights, the latter varying from 14.000 for the lead-containing polymer to 110.000 for the 1,4-divinylbenzene adduct. Reactions of triphenyltin hydride and diphenyltin dihydride with mono- and di-p-styrenyl derivatives of germanium, tin, and lead yielding monomeric compounds containing two and three hydrocarbon-linked metal atoms were carried out as well. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 30, 1960
- Accession Number
- AD0640553
Entities
People
- G. J. M. Van Der Kerk
- J. G. Noltes