THE BEHAVIOR OF NITRIC ACID, ETHYL NITRATE AND NITRIC ANHYDRIDE IN SULFURIC ACID SOLUTION,

Abstract

Evidence based upon spectroscopic and cryoscopic data and upon chemical reactivity indicates that nitric acid, nitric anhydride and ethyl nitrate yield NO2(+) ions in sulfuric acid solution, substantiating the results of previous investigators. A parallel is drawn between the ionization of these substances and the complex ionization of certain organic acids in sulfuric acid. The results are in accord with the currently accepted theory of the mechanism of nitration with mixed acids. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1947
Accession Number
AD0640600

Entities

People

  • L. P. Kuhn

Organizations

  • Ballistic Research Laboratory

Tags

DTIC Thesaurus Topics

  • Acids
  • Anhydrides
  • Chemical Compounds
  • Ionization
  • Nitration
  • Nitric Acid
  • Organic Acids
  • Reactivities

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Organic Chemistry