RESEARCH ON SILICON AND PHOSPHORUS DERIVATIVES OF VARIOUS NITROGEN COMPOUNDS.
Abstract
Trialkyl phosphites or diphenyl alkyl phosphites react with cyanuric chloride to give alkyl halides and 2,4,6-tris(dialkyl-phosphonato)-s-triazines or 2,4,6-tris(diphenylphosphonato)-s-triazines. Triphenyl phosphite reacts with cyanuric chloride to form triphenyl cyanurate and diphenylphosphorochloridite, (PhO)2PC1. Improved methods of synthesis of 2,4,6-tris(diphenylphosphino)-s-triazine were investigated and the trisulphide and triselenide were prepared. Cyanuric chloride reacts with NN-diethylaniline to give 2,4-dichloro-6-N-ethylanilino-s-triazine and 2,4-dichloro-6-p-NN-diethylanilino-s-triazine. The compounds tris(trimethylsilyl)amine, bis(trimethylsilyl)-triphenylsilylamine, dimethylchlorosilylbis(trimethylsilyl)amine, diethylchlorosilylbis(trimethylsilyl)amine, and diphenylchlorosilylbis(trimethylsilyl)amine have been prepared from reactions of hexamethyldisilazyl-lithium. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 31, 1962
- Accession Number
- AD0640796
Entities
People
- Robert A. Shaw
Organizations
- Birkbeck, University of London