GAS-LIQUID CHROMATOGRAPHY OF THE ALKYL ALPHA CYANOACRYLATES

Abstract

The purity of the cyanoacrylate monomers was estimated by gas- chromatographic technique. Some of the impurities, like diglyme, cyanoacetates, were identified by noting the retention volumes. A plot of the retention volumes vs. number of carbons in the alkyl part of the cyanoacrylates was found to be linear; however, the use of temperature programming to obviate the broadening of the peaks for compounds having higher retention volumes was not successful, due to the shifting of the base line with increase in temperature.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1966
Accession Number
AD0641120

Entities

People

  • Duane E. Bartak
  • R. K. Kulkarni

Organizations

  • Walter Reed Army Medical Center

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Abstracts
  • Alkenes
  • Base Lines
  • Chlorides
  • Chromatographs
  • Chromatography
  • Classification
  • Commercial Equipment
  • Computer Programming
  • Cyanoacrylates
  • Detectors
  • Flow Rate
  • Gases
  • Identification
  • Impurities
  • Liquid Chromatography
  • Materials

Fields of Study

  • Chemistry

Readers

  • Mathematics or Statistics
  • Organic Chemistry
  • Polymer Science and Engineering.