PHOSPHORUS-NITROGEN COMPOUNDS,

Abstract

Diphenylphosphinic amide reacts with PC15 forming chlorodiphenyl phosphine imine hydrochloride, ((C6H5)2P(C1)NH2)C1. This compound is easily hydrolyzed to diphenylphosphinate, reacts with further PC15 to the phosphorus nitride salt ((C6H5)2P(C1)=N-PC13)(PC16), and is decomposed at 270-290C giving ((C6H5)2PN)3 (yield: 51%) and ((C6H5)2PN)4 (30%). (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1965
Accession Number
AD0642394

Entities

People

  • Margot Becke-goehring

Organizations

  • Heidelberg University

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Elements
  • Group 15 Elements
  • Nitrogen
  • Nitrogen Compounds
  • Nonmetals
  • Organophosphorus Compounds
  • Phosphine
  • Phosphorus

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry