EXPERIMENTAL STUDY OF THE DEFLAGRATION OF GASES AND SOLIDS.

Abstract

First a general survey is given of the research undertaken under this grant. Three topics have progressed during the last year in a sufficient manner as to be reported in this document. (I) Burning velocity, flame temperature and reaction zone thickness are reported for gaseous mixtures of hydrogen cyanide, oxygen and nitrogen at different richnesses and dilutions. Accepting the model of an homogeneous reaction for the flame reaction zone, global activation energies and reaction orders are derived. (II) The application of a new technique (simulating burner) allows the estimation of the amount of heat transferred from the flame reaction zone upstream to the burning surface of a solid propellant. Some preliminary data are presented for given conditions of flow and zeroeth degree of mixedness in the preparation zone upstream of the flame. (III) The comparative intensities of CH or C2 show that the yield of excited C2 or CH radicals per molecule of fuel oxidized in the flame is about 1.4 times larger in isobutane than in normal butane flames (with oxygen) at the same richness and degree of dilution with nitrogen. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1966
Accession Number
AD0643439

Entities

People

  • A. Van Tiggelen

Organizations

  • UCLouvain

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Alkanes
  • Chemical Reaction Properties
  • Chemical Reactions
  • Combustion
  • Cyanides
  • Deflagration
  • Dilution
  • Energy
  • Heat Of Activation
  • Hydrogen
  • Hydrogen Cyanide
  • Intensity
  • Nitrogen
  • Propellants
  • Reaction Orders
  • Solid Propellants

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry