TRANSITION METAL COMPLEXES WITH TWO NEW SERIES OF TETRADENTATE LIGANDS.

Abstract

An investigation was undertaken of the coordinating properties of flexible tetradentate phosphorus, arsenic, and nitrogen ligands of the type D(CH2CH2CH2D')3, (where D does not = D'). A series of nickel (II) complexes with the five coordinate (Ni(ligand)X)(+) cations was isolated and studied extensively. A number of Pd(II) and Co(II) complexes were also examined. A second series of studies involved the nature of bonding in boron-transition metal complexes having groups of the type B(OCH2CH2NR2). Also, the synthesis of a number of tetradentate compounds with boron-carbon bonds was undertaken (e.g., B(Ph-AsO2)3).

Document Details

Document Type
Technical Report
Publication Date
Nov 14, 1966
Accession Number
AD0646013

Entities

People

  • Devon W. Meek

Organizations

  • Ohio State University

Tags

DTIC Thesaurus Topics

  • Coordination Complexes
  • Elements
  • Group 15 Elements
  • Metals
  • Nitrogen
  • Nonmetals
  • Phosphorus
  • Transition Metals
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry