BASIC RESEARCH ON SYNTHESIS OF NEW PHOSPHORUS-NITROGEN REAGENTS.

Abstract

Two compounds of the general formula (RO)2P-ONHP-O(OR)2 were prepared and applied in the preparation of metal derivatives. Tetraethyl imidodiphosphate and tetraphenyl imidodiphosphate were prepared by published methods. New crystalline derivatives were obtained for the first compound with zinc, for the second compound with zinc, palladium, lanthanum, cerium, praseodymium and europium. A tetramminepalladium (II) derivative of tetraphenyl imidodiphosphate is promising for the gravimetric determination of palladium. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1966
Accession Number
AD0646745

Entities

People

  • Morris L. Nielsen

Organizations

  • Monsanto

Tags

DTIC Thesaurus Topics

  • Elements
  • Europium
  • Group 15 Elements
  • Lanthanum
  • Metals
  • Nitrogen
  • Palladium
  • Phosphorus
  • Praseodymium
  • Rare Earth Elements

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Organic Chemistry