ADVANCED OXIDIZER CHEMISTRY.

Abstract

The structure of O2BF4 and the kinetics of decomposition of O2BF4 were studied. More experiments have to be completed, but it seems certain that the structure is O2(+)BF4(-). The decomposition of O2BF4 is best explained by: O2BF4 (s) reversibly yields O2F (g) + BF3 (g) and 2O2F yields 2O2 + F2. The reactions of O2F2 and O4F2 with nitrogen oxides produced some interesting results, but no new compounds were isolated. Some evidence for NO2OOF was obtained, but if this compound exists, it readily decomposes to O2 and NO2F. (Author)

Document Details

Document Type
Technical Report
Publication Date
Nov 18, 1966
Accession Number
AD0646779

Entities

People

  • Irine J. Solomon

Organizations

  • IIT Research Institute

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Decomposition
  • Kinetics
  • Nitrogen
  • Nitrogen Oxides
  • Oxides

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry