HIGH PERFORMANCE THIN FILMS FOR MICROCIRCUITS.

Abstract

A new sputtering system was designed and built with a vertical arrangement of electrodes to permit deposition of metal films free from pin holes. A hexagonally shaped substrate holder, which rotates to six different positions, allows performance of five sputtering runs without breaking the vacuum. A sputtering rate as high as 1500 A/min was achieved. A number of thin film hafnium dioxide capacitors were fabricated onto silicon substrates. Three different approaches were tested: (1) Silicon substrates passivated with a thermally grown oxide are used without making electrical contact between the hafnium film and the silicon substrates. (2) Windows etched into the SiO2 layer established ohmic contact between the silicon substrate (P-type) and the hafnium film which is partically converted into dielectric hafnium dioxide. (3) Hafnium metal completely converted into oxide. In another series of experiments, metal oxide semiconductor transistors were fabricated and studied with anodically formed HfO2 used as the gate insulator. A surface state density, N sub ss, of 13 x 10 to the 11th power states/sq cm was determined by capacitance - voltage measurements. This performance is comparable to thermally grown SiO2. The main advantage in using HfO2 for gate insulators are the high dielectric constant and the good dielectric properties of anodically grown oxides. (Author)

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1967
Accession Number
AD0647891

Entities

People

  • Franz Huber
  • Walter Witt
  • William Laznovsky

Tags

DTIC Thesaurus Topics

  • Dielectric Permittivity
  • Dielectric Properties
  • Dielectrics
  • Films
  • Metal Films
  • Metal Oxide Semiconductors
  • Metal Oxides
  • Metal-Semiconductor Junctions
  • Oxides
  • Semiconductor Devices
  • Semiconductors
  • Sputtering
  • Substrates
  • Thin Films
  • Transistors

Readers

  • Semiconductor Device Technology
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene