TERTIARY PHOSPHINE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II).
Abstract
The results are reported of research which was undertaken (1) to determine the chemical shifts of cis and trans isomers of platinum(II) complexes in hope of gaining information about pi-bonding in the Pt-P bond, and to extend this study to palladium(II); (2) to determine trends which may exist within a series of ligands for the purpose of developing expressions that would enable calculation of chemical shifts for complexes; (3) to expand the knowledge of the chemistry of tertiary phosphine complexes of platinum(II) and palladium(II); and (4) to determine phosphorus-phosphorus coupling constants by preparing a complex of a chelating diphosphine (R2PCH2CH2PR'2) or by preparing a complex containing two different phosphines.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jun 01, 1967
- Accession Number
- AD0654328
Entities
People
- Richard Lee Keiter
Organizations
- University of Maryland