PROPERTIES AND STRUCTURES OF HETEROPOLY BLUES.
Abstract
The work established that heteropoly blues are discrete anionic species, almost certainly isostructural with the oxidized anions. Heteropoly tungstates can be reduced in one-electron steps and the corresponding molybdates only in two-electron steps, a difference for which there is no immediately obvious explanation. Addition of electrons markedly affects the stability of the heteropoly structures, which become increasingly inert towards alkaline degradation upon reduction. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- May 13, 1967
- Accession Number
- AD0654767
Entities
People
- Michael T. Pope
Organizations
- Georgetown University