ELECTRONIC SPECTRA OF AZA-AROMATICS IN POLYMER MATRICES.

Abstract

The absorption and fluorescence of acridine, phenazine, their cations, and phenazine-di-N-oxide were studied in polymer matrices. The correspondence to spectra in liquid or frozen solutions is established for the polymer matrices. The effect of the matrix and compression (0-27 kbar) on the spectral properties are compared. The extent of solid solvent perturbation on spectral location and bandwidth is illustrated for acridine and phenazine. The red shifts of the absorption and fluorescence band maxima are compared for two polymer matrices. The magnitude of the pressure response of the fluorescence bands and intensities differs for degassed and nondegassed plastic solutions. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1967
Accession Number
AD0655464

Entities

People

  • A. H. Kadhim
  • E. H. Park
  • H. W. Offen

Organizations

  • University of California, Santa Barbara

Tags

DTIC Thesaurus Topics

  • 3-Ring Heterocyclic Compounds
  • Absorption
  • Acridines
  • Bandwidth
  • Chemical Compounds
  • Compression
  • Cyclic Compounds
  • Fluorescence
  • Heterocyclic Compounds
  • Intensity
  • Organic Compounds
  • Perturbations
  • Spectra

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Linear Algebra
  • Polymer Science and Technology

Technology Areas

  • Microelectronics