ALUMINIUM-NITROGEN AND ALUMINIUM-PHOSPHORUS POLYMERS

Abstract

The products of the reaction between methylamine and trialkylaluminiums were studied by molecular weight determinations as well as by infrared and nuclear magnetic resonance spectroscopy. Stereoisomers of (R2A1NHR)3 are indicated. The reactions of phosphine adducts of organoaluminium compounds were studied and an order of base strength with respect to triethylaluminium was established by displacement reactions. Polymers of composition (RA1PR)x were prepared but crystalline products were obtained. Aluminium-nitrogen seem to be more stable than corresponding aluminium- phosphorus frameworks.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1967
Accession Number
AD0655807

Entities

People

  • Antony R. Cullingworth
  • Donald Wharmby
  • J. David Smith
  • Keith Gosling

Organizations

  • University of Sussex

Tags

Communities of Interest

  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Air Force
  • Alkanes
  • Aluminum
  • Amines
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Displacement Reactions
  • Governments
  • Magnetic Resonance
  • Materials
  • Materials Laboratories
  • Molecular Weight
  • Organic Chemistry
  • Organophosphorus Compounds
  • Phosphorus Compounds
  • Resonance

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry