DEUTERIUM ISOTOPE STUDIES ON 2,3-DICARBAHEXABORANE(8).

Abstract

Deuterium exchange at various positions on the C2B4H8 molecule was studied. D2 exchanges with all boron-bonded hydrogen atoms, and B2D6 in the presence of diglyme exchanges only at the 4-, 6-terminal positions. The (CH3)2C2B4H6-DCl exchange, catalyzed by aluminum chloride, occurs at both apex and base terminal positions. C,C-Dideuterio-2,3-dicarbahexaborane(8), D2C2B4H6, was prepared for comparison of the infrared spectrum. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1967
Accession Number
AD0657174

Entities

People

  • Gary B. Dunks
  • James E. Scott Jr.
  • John R. Spielman
  • Richard Warren
  • Thomas Onak

Organizations

  • California State University, Los Angeles

Tags

DTIC Thesaurus Topics

  • Aluminum
  • Chlorides
  • Deuterium
  • Diffraction
  • Electromagnetic Spectra
  • Elements
  • Hydrogen
  • Infrared Spectra
  • Molecules
  • Spectra
  • Terminals
  • Wave Phenomena

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry