PREPARATIVE SCALE GAS-LIQUID CHROMATOGRAPHY OF SUBSTITUTED DIAZIRINES,

Abstract

The heretofore unseparated reaction mixture resulting from the reaction of acetamidine hydrochloride with sodium hypobromite has been resolved into two pure substances: 3-chloro-3-methyldiazirine and 3-bromo-3-methyldiazirine, using preparative scale gas-liquid chromotography (GLC). The general utility of this method of purification has been extended to a series of substituted diazirines. In all cases, the resultant material was free from either contaminants or decomposition products. Product identification was accomplished by utilizing infrared and ultraviolet spectroscopy and mass spectrometry. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1967
Accession Number
AD0658988

Entities

People

  • James A. Merritt
  • Lawrence C. Robertson
  • Ronald W. Mitchell
  • William N. Knopka

Organizations

  • United States Army Aviation and Missile Command

Tags

DTIC Thesaurus Topics

  • Analytical Chemistry Techniques
  • Chromatography
  • Decomposition
  • Environmental Pollutants
  • Identification
  • Liquid Chromatography
  • Mass Spectrometry
  • Materials
  • Spectrometry
  • Spectroscopy
  • Ultraviolet Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry