LCAO SECULAR DETERMINANT PROGRAM

Abstract

The report describes a computer program designed to set up the secular determinant arising from an energy band calculation in the LCAO (Linear Combination of Atomic Orbitals) approximation. The program determines which transfer integrals vanish, and which are related; further, it computes the appropriate structure factor (which contains the momentum dependence) for each entry in the secular determinant. This program can handle arbitrary crystal symmetry, unit cells with many inequivalent atoms, interactions involving up to fourth-nearest neighbors, and a choice of s-, p-, and/or d-orbitals on the various inequivalent atoms. The transfer integrals are left as parameters to be determined from the eigenvalues corresponding to special symmetry points in the Brillouin zone.

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Document Details

Document Type
Technical Report
Publication Date
Jul 12, 1967
Accession Number
AD0659749

Entities

People

  • D. Esterling

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Atomic Orbitals
  • Atoms
  • Band Theory Of Solids
  • Brillouin Zones
  • Cartesian Coordinates
  • Classification
  • Coefficients
  • Computer Programs
  • Computers
  • Coordinate Systems
  • Crystals
  • Energy Bands
  • Equations
  • Procedures (Computers)
  • Security
  • Translations

Readers

  • Computer Science.
  • Plasma Physics / Magnetohydrodynamics
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Space
  • Space - Orbital Debris