HALOGENATED HYDROCARBONS. PART 2. DECOMPOSITION OF SELECTED CHLORINATED HYDROCARBONS OVER HOPCALITE CATALYST

Abstract

A study was made of the decomposition of several chlorocarbons in air when exposed to Hopcalite catalyst in a laboratory reactor from 50 to 350 C. The chlorocarbons studied were methyl chloroform, vinylidene chloride, trichloroethylene and tetrachloroethylene. At 300 C the percentage decomposition ranged from 70% for tetrachloroethylene to 100% for methyl chloroform. All yielded substantial amounts of hydrochloric acid as they decomposed. Yields of organic compounds during the decomposition of the chlorocarbons were quite small, except in the case of methyl chloroform, which yielded as much as 50% of vinylidene chloride.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jul 20, 1967
Accession Number
AD0659956

Entities

People

  • J. E. Johnson
  • Richard H. Gammon

Organizations

  • United States Naval Research Laboratory

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Carbon Tetrachloride
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chlorides
  • Chlorinated Hydrocarbons
  • Chlorine
  • Chlorine Compounds
  • Combustion
  • Detectors
  • Halogenated Hydrocarbons
  • Hydrocarbons
  • Nuclear Powered Submarines
  • Organic Compounds
  • Pyrolysis
  • Submarine Atmospheres
  • Submarines

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Geochemistry
  • Materials Science and Engineering.