PERCHLORIC ACID FLAMES. PART VII. MIXED FUEL-RICH FLAMES.

Abstract

Fuel-rich perchloric acid flames containing binary mixtures of hydrocarbons (methane-ethane, methane-ethylene and ethane-ethylene) as fuels were studied by sampling the burnt gas products for a range of mixtures of each pair of fuels. It was shown that there is selective consumption of one member of each fuel pair and that the order of increasing resistance to attack is ethane < ethylene < methane. Approximate ratios of the rate constants for the attack on the fuels are deduced and compared with the literature values for hydrogen, oxygen and chlorine atom and hydroxyl radical attack on the same hydrocarbons. It is concluded that the results provide additional support for a mechanism involving chlorine-oxygen species. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1967
Accession Number
AD0661595

Entities

People

  • G. S. Pearson

Tags

DTIC Thesaurus Topics

  • Acids
  • Acyclic Hydrocarbons
  • Alkenes
  • Chemical Compounds
  • Chlorine
  • Ethylenes
  • Hydrocarbons
  • Hydrogen
  • Hydroxyl Radical
  • Literature
  • Organic Compounds
  • Perchloric Acid
  • Resistance
  • Sampling

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry