RESEARCH IN SYNTHESIS AND CHARACTERIZATION OF HIGHLY ARYLATED ORGANOSILICON COMPOUNDS.

Abstract

A series of six organomonofluorosilanes was prepared via the corresponding chlorosilane analogs by derivatization of the appropriate chlorosilane intermediates with 1-naphthyllithium followed by rehalogenation with a suitable inorganic fluoride. Aqueous hydrofluoric acid (10%) was used in all but the single case of an Si-H-containing compound for which a hexafluorosilicic acid reagent was found to be satisfactory. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1967
Accession Number
AD0663240

Entities

People

  • D. C. Smith
  • G. M. Hart
  • J. W. Ezell
  • K. C. Pande
  • S. R. Gudemoos

Tags

DTIC Thesaurus Topics

  • Acids
  • Chemical Compounds
  • Fluorides
  • Fluorine Compounds
  • Halides
  • Hydrofluoric Acid
  • Organosilicon Compounds

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry