A FLUORINE-19 NMR STUDY OF SOME DIADDUCTS OF TITANIUM TETRAFLUORIDE.

Abstract

Several series of the diadducts of titanium tetrafluoride were studied with high-resolution fluorine-19 nuclear magnetic resonance (nmr) spectroscopy. These series consisted of fluorotitantate complexes of formula TiF4.2(donor) and TiF5.(donor)(-1), where donor represents an organic molecule (Lewis base) which coordinates through oxygen. The TiF4.2(donor) adducts included both TiF4.2D (D = donor) complexes, in which the donors are identical, and TiF4.D,D' complexes, in which D and D' represent different Lewis bases. Fluorine-19 chemical shifts and spin-spin coupling constants were determined for most of these fluorotitanate complexes. The temperature dependence of the TiF4.2D spectra was also studied. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1967
Accession Number
AD0666658

Entities

People

  • Daniel S. Dyer

Organizations

  • Air Force Research Laboratory

Tags

DTIC Thesaurus Topics

  • Chemical Shifts
  • Fluorine
  • High Resolution
  • Lewis Bases
  • Magnetic Resonance
  • Nuclear Magnetic Resonance
  • Quantum Properties
  • Resonance
  • Spectra
  • Spectroscopy
  • Titanium

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry