NEW IRON-CONTAINING MONOMERS AND POLYMERS FROM FIVE-MEMBERED NAPHTHENES,
Abstract
The alkylation of ferrocene by different olefins (iso- C4H8, iso-C5H10, and iso-C8H16) in the presence of 25% H3PO4 is described. BF3 at the optimum conditions of 60C and a 5-hr. agitation period, is compared. With an increase in olefin molecular weight, there is a decrease in alkylate yield and ferrocene conversion accompanied by an increase of monoalkylferrocene content. The physical-chemical properties of the prepared alkylferrocenes are listed. Ferrocene and alkylferrocene were then used to obtain ferrocenyl-containing polymers by the polyrecombination reaction which consists of peroxide treatment at 170-200C. The joint polyrecombination of ferrocene with paradichlorobenzene, diphenol, alpha-bromonaphthalene and quinoline was also investigated and the data are tabulated. Soluble polymers were obtained by the polycondensation of ferrocene with acetone in the presence of ZnCl2 + HCl. The preparation of polyferrocenylvinylene from acetylferrocene is described. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 29, 1967
- Accession Number
- AD0668062
Entities
People
- F. F. Machus
- I. I. Patalakh
- T. A. Sokolinskaya
- T. P. Vishnyakova
- Ya. M. Paushkin
Organizations
- National Air and Space Intelligence Center