FORCE CONSTANTS OF NONMETAL FLUORIDES: THE VIBRATIONAL ASSIGNMENT OF IF6(+).

Abstract

The force constants of a series of nonmetal hexafluorides were calculated using a modified Urey-Bradley Force Field, and the results correlated according to the position of the central atom in the periodic table. On this basis, the recent vibrational assignment of IF6(+) by Christe and Sawodny was questioned; it is suggested that the nu1 and nu2 assignments should be reversed, and that nu4 has not been properly identified. (Author)

Document Details

Document Type
Technical Report
Publication Date
May 01, 1968
Accession Number
AD0670554

Entities

People

  • George E. Leroi
  • John L. Hardwick

Organizations

  • Michigan State University

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Cooperation
  • Fluorides
  • Nonmetals

Readers

  • Materials Science and Engineering.
  • Spectroscopy.
  • Systems Analysis and Design