A CHEMICAL KINETIC STUDY OF SUBSTITUTION REACTION IN COORDINATION COMPOUNDS INVOLVING TRANSITION-METAL IONS HAVING THE D8 ELECTRONIC CONFIGURATION.

Abstract

Detailed studies were completed of the kinetics and mechanisms of the acid hydrolyses of the Ni(II) and Pd(II) complexes with ethylenebisbiguanide. The stability constant for the Ni(II) complex with ethylenebisbiguanidde was determined. Employing a computer program developed from evaluating the ionization constants of ethylene bisbiguanidinium ion, the two acid dissociation constants of squaric acid were redetermined. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1968
Accession Number
AD0672001

Entities

People

  • David J. Macdonald

Organizations

  • University of Nevada, Reno

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Reactions
  • Computer Programs
  • Computers
  • Dissociation
  • Ethylenes
  • Ionization
  • Kinetics
  • Metals
  • Substitution Reactions
  • Transition Metals
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Molecular Photonics/Laser Physics
  • Organic Chemistry

Technology Areas

  • Microelectronics