PRESSURE DEPENDENCE OF ELECTROLYTIC CONDUCTANCE.

Abstract

Conductances as a function of pressure at 30C were measured for the following systems: tetra-iso-amylammonium picrate in diethyl ether, benzene and anisole; sodium bromide, tetramethyl ammonium bromide,tetrabutyl ammonium bromide and tetrabutyl ammonium tetraphenylboride in methanol and in ethanol. The pressure range extended to 5000 atmospheres (except for benzene, which freezes under a pressure of about 750 atmospheres). Densities and dielectric constants under pressure were measured for toluene, o-xylene, p-xylene, cumene, diethyl ether, di-n-propyl ether, anisole, n-butyl chloride, chlorobenzene, 1,1-dichlorethane, 1,2-dichloroethane, and 1,2-dibromoethane. Viscosities under pressure were measured for n-propyl ether, diethyl ether, isopropanol, cumene, n-butyl chloride and 1,2-dichloroethane. Apparatus and methods for measuring conductance, dielectric constant, density and viscosity under high pressure are described. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1968
Accession Number
AD0672277

Entities

People

  • Raymond M. Fuoss

Organizations

  • Yale University

Tags

DTIC Thesaurus Topics

  • Alcohols
  • Atmospheres
  • Chemical Compounds
  • Chlorides
  • Chlorobenzene
  • Dielectric Permittivity
  • High Pressure
  • Methanols
  • Organic Compounds
  • Viscosity

Fields of Study

  • Chemistry
  • Environmental science

Readers

  • Analytical Chemistry
  • Organic Chemistry
  • Thermal Physics or Thermal Science.