DISUBSTITUTED PARAPHENYLENE MONOMERS. ALPHA-METHYL- AND ALPHA-PHENYL-VINYL DERIVATIVES OF BENZENE, BIPHENYL, P-TERPHENYL, AND P,P'-DIPHENOXYBIPHENYL,

Abstract

The high-yield syntheses of bis(p-(alpha-methylvinyl)) monomers of benzene, biphenyl, p-terphenyl, and 4,4'-diphenoxybiphenyl are reported. Also described are the syntheses of new bis(p-(alpha-phenylvinyl)) monomers of biphenyl, p-terphenyl, and 4,4'-diphenoxybiphenyl. Infrared spectral data for the diolefinic monomers and their precursors are presented, together with brief details for the polymerization of the diolefins by means of free radical and Lewis acid catalysts. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1968
Accession Number
AD0675062

Entities

People

  • Robert W. Rosser
  • Roy G. Neville

Organizations

  • Boeing

Tags

DTIC Thesaurus Topics

  • Acids
  • Biphenyl
  • Catalysts
  • Chemical Compounds
  • Free Radicals
  • Lewis Acids
  • Polymerization
  • Precursors

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology