NO2 CHEMILUMINESCENT WAKE RADIATION.

Abstract

A flow field and chemical kinetics model is presented for calculating the NO + O to NO2 + photon chemiluminescence wake emission. Numerical results are compared to the wake measurements made by Reis in a ballistic range. The wake NO2 chemiluminescence intensity tends to peak at several hundred body diameters, decreasing in intensity in the far wake. The far-wake structure of these profiles is fit well by our calculations. Peaking of the intensity is due mainly to the drop in the mean wake temperature; final decay is shown to be caused both by atomic O cleanup and by dilution in the growing turbulent wake. For pure air the cleanup reactions are due to NO + O + N2 to NO2 + N2 and O2 + O + N2 to O3 + N2. However, for the ballistic range conditions with approximately 0.01% H2O contamination, the O cleanup was dominated by a reaction chain involving atomic hydrogen. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1968
Accession Number
AD0675529

Entities

People

  • M. Camac
  • R. L. Schapker

Tags

DTIC Thesaurus Topics

  • Chemical Kinetics
  • Chemiluminescence
  • Contamination
  • Diameters
  • Dilution
  • Emission
  • Flow
  • Flow Fields
  • Hydrogen
  • Intensity
  • Kinetics
  • Measurement
  • Radiation

Fields of Study

  • Physics

Readers

  • Environmental Remediation and Restoration.
  • Fluid Mechanics and Fluid Dynamics.
  • Molecular Photonics/Laser Physics