COMBUSTION KINETICS OF TETRAFLUOROETHYLENE.

Abstract

The pyrolysis of C2F4, C3F6, and CF2O were studied in the temperature and pressure ranges 300-455C, 25-760 torr; 550-675C, 50-410 torr; and 330-480C, 25-600 torr, respectively. The rate equations and appropriate Arrhenius rate constants for these three reactions are reported. The oxidation kinetics of C2F4 are also being investigated and preliminary results in the temperature and pressure ranges 175-300C and 25-200 torr are discussed. Finally the application of gas-solid chromatography techniques to the separation of low molecular weight fluorocarbons and the analysis of the C2F4 oxidation products are discussed. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1968
Accession Number
AD0676680

Entities

People

  • Richard A. Matula

Organizations

  • University of Michigan

Tags

DTIC Thesaurus Topics

  • Chemical Reaction Properties
  • Chemical Reactions
  • Chromatography
  • Combustion
  • Equations
  • Exothermic Reactions
  • Fluorinated Hydrocarbons
  • Fluoropolymers
  • Kinetics
  • Mathematics
  • Molecular Weight
  • Oxidation
  • Pyrolysis

Fields of Study

  • Chemistry

Readers

  • Hydraulic Engineering.
  • Organic Chemistry