INFLUENCE OF CONCENTRATION OF WATER AND COMPOSITION OF FATTY ACIDS ON STRUCTURE AND PROPERTIES OF SYNTHETIC LUBRICANT GREASES,

Abstract

A series of greases were prepared from the residue of the synthesis of synthetic fatty acids (acid number 103 mg KOH/g), C5-C9 acids (280 mg KOH/g), and acid water (248 mg KOH/g); the dispersion medium was a mixture of Z spindle oil and S machine oil. This composition corresponds to that of commercial synthetic grease. It was found that a change in the water content of the greases in the range of 1 to 5% does not affect their volume mechanical properties or structure, indicating that it is desirable to raise the water content of such greases to 4-5%. The structure of hydrated calcium lubricants prepared from soaps of narrow fractions of heat-treated and distilled synthetic fatty acids and their mixtures differs from the structure of fatty and synthetic greases in that it consists of rod-shaped, petal-shaped, and flaky soap crystallites. The greatest thickening capacity is displayed by C16-C20 acids with an average molecular weight of 286-300 and a purity of the fraction of no less than 90-95%. A wide boiling fraction of C13-C22 acids with a purity of no less than 98% is recommended for practical application and for producing high-quality synthetic grease. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 05, 1967
Accession Number
AD0677253

Entities

People

  • M. B. Nakonechnaya
  • N. K. Mankovskaya
  • V. A. Prokopchuk
  • V. V. Sinitsyn
  • Yu. L. Ishchuk

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Crystallites
  • Dispersions
  • Fatty Acids
  • Lubricants
  • Mechanical Properties
  • Molecular Weight
  • Specialty Uses Of Chemicals
  • Synthetic Lubricants

Readers

  • Analytical Chemistry
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Petroleum Engineering